WEKO3
インデックスリンク
アイテム
Experimental and Theoretical Studies on the Self-assembled Nano-structure of Nonionic Surfactant/ionic Liquid Hybrid Systems
http://hdl.handle.net/10935/0002006083
http://hdl.handle.net/10935/0002006083790f2d02-8200-4fa2-be5c-fd9f292e0ecc
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
https://iopscience.iop.org/article/10.1088/1742-6596/2610/1/012064
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| アイテムタイプ | default_学術雑誌論文 / Journal Article(1) | |||||||||
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| タイトル | ||||||||||
| タイトル | Experimental and Theoretical Studies on the Self-assembled Nano-structure of Nonionic Surfactant/ionic Liquid Hybrid Systems | |||||||||
| 言語 | en | |||||||||
| 言語 | ||||||||||
| 言語 | eng | |||||||||
| キーワード | ||||||||||
| 言語 | en | |||||||||
| 主題Scheme | Other | |||||||||
| 主題 | nonionic surfactant/ionic liquids hybrid systems | |||||||||
| キーワード | ||||||||||
| 言語 | en | |||||||||
| 主題Scheme | Other | |||||||||
| 主題 | SAXS | |||||||||
| キーワード | ||||||||||
| 言語 | en | |||||||||
| 主題Scheme | Other | |||||||||
| 主題 | DFT calculation | |||||||||
| キーワード | ||||||||||
| 言語 | en | |||||||||
| 主題Scheme | Other | |||||||||
| 主題 | configurations | |||||||||
| キーワード | ||||||||||
| 言語 | en | |||||||||
| 主題Scheme | Other | |||||||||
| 主題 | inter-molecular interactions | |||||||||
| キーワード | ||||||||||
| 言語 | en | |||||||||
| 主題Scheme | Other | |||||||||
| 主題 | Ionic liquids | |||||||||
| 資源タイプ | ||||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||||
| 資源タイプ | journal article | |||||||||
| アクセス権 | ||||||||||
| アクセス権 | metadata only access | |||||||||
| アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||||||
| 著者 |
Zhu Jingjing
× Zhu Jingjing
× Hua Er
× 原田 雅史 |
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| 抄録 | ||||||||||
| 内容記述タイプ | Abstract | |||||||||
| 内容記述 | The self-assembled structure of various Brij series nonionic surfactants (such as Brij-30, Brij-52, Brij-56, Brij-58, Brij-35, and Brij-700) hybridized with room-temperature ionic liquids (RTILs) was studied using small-angle X-ray scattering (SAXS) measurements and DFT calculations. The detailed characterization of the obtained self-assembled structure in nonionic surfactant/RTILs hybrid system was carried out using the combination of SAXS and DFT calculations. The SAXS result indicates that the alkyl chain length dependence on the spatial correlation corresponds to the interference peak angle. The addition of Brij surfactant to the [BMIm][PF6] results in a drastic change in the interference peak position. The DFT calculation result shows that a weak hydrogen bonding was formed between the −CH, −F of RTILs ([BMIm][PF6] and [OMIm][PF6]) and the polar site −OH, −O − of surfactants (Brij-30 and Brij-56). When the mixing molar ratio of ILs/Brij is 1:1, the absolute value of interaction energy (ΔE0BSSE) is 8.10-1.43 and 4.22-0.90 kcal·mol-1 for ILs/Brij-30 and ILs/Brij-56, respectively. Meanwhile, in the case of the ILs/Brij molar ratio equal to 2:1, ΔE0BSSE is 19.14-1.79 and 12.39-1.45 kcal·mol-1, respectively. It suggests that the stability of ILs/Brij hybridized system is higher for ILs/Brij-30 than for ILs/Brij56, and it has an increasing tendency to some extent with an increase of the molar fraction of ILs. | |||||||||
| 言語 | en | |||||||||
| 書誌情報 |
en : Journal of Physics: Conference Series 巻 2610, 号 1, p. 12064, 発行日 2023 |
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| 出版者 | ||||||||||
| 出版者 | Institute of Physics Publishing | |||||||||
| 言語 | en | |||||||||
| ISSN | ||||||||||
| 収録物識別子タイプ | EISSN | |||||||||
| 収録物識別子 | 1742-6596 | |||||||||
| DOI | ||||||||||
| 識別子タイプ | DOI | |||||||||
| 関連識別子 | 10.1088/1742-6596/2610/1/012064 | |||||||||
| 権利 | ||||||||||
| 権利情報Resource | https://creativecommons.org/licenses/by/3.0/deed.en | |||||||||
| 権利情報 | Creative Commons Attribution 3.0 licence | |||||||||
| 言語 | en | |||||||||
