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Creation of Polymer Hydrogelator/Poly(Vinyl Alcohol) Composite Molecular Hydrogel Materials
http://hdl.handle.net/10935/0002005889
http://hdl.handle.net/10935/0002005889d0dfc1dd-5554-4181-a7d3-def7a05272a0
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
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| アイテムタイプ | default_学術雑誌論文 / Journal Article(1) | |||||||
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| タイトル | ||||||||
| タイトル | Creation of Polymer Hydrogelator/Poly(Vinyl Alcohol) Composite Molecular Hydrogel Materials | |||||||
| 言語 | en | |||||||
| 言語 | ||||||||
| 言語 | eng | |||||||
| キーワード | ||||||||
| 言語 | en | |||||||
| 主題Scheme | Other | |||||||
| 主題 | polymer hydrogelator | |||||||
| キーワード | ||||||||
| 言語 | en | |||||||
| 主題Scheme | Other | |||||||
| 主題 | molecular hydrogel | |||||||
| キーワード | ||||||||
| 言語 | en | |||||||
| 主題Scheme | Other | |||||||
| 主題 | thixotropic behavior | |||||||
| キーワード | ||||||||
| 言語 | en | |||||||
| 主題Scheme | Other | |||||||
| 主題 | poly(vinyl alcohol) | |||||||
| キーワード | ||||||||
| 言語 | en | |||||||
| 主題Scheme | Other | |||||||
| 主題 | composite | |||||||
| 資源タイプ | ||||||||
| 資源タイプ識別子 | http://purl.org/coar/resource_type/c_6501 | |||||||
| 資源タイプ | journal article | |||||||
| アクセス権 | ||||||||
| アクセス権 | metadata only access | |||||||
| アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||||
| 著者 |
大背戸, 豊
× 大背戸, 豊× Ueno, Wakana
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| 抄録 | ||||||||
| 内容記述タイプ | Abstract | |||||||
| 内容記述 | Polymer hydrogels, including molecular hydrogels, are expected to become materials for healthcare and medical applications, but there is a need to create new functional molecular gels that can meet the required performance. In this paper, for creating new molecular hydrogel materials, the gel formation behavior and its rheological properties for the molecular gels composed of a polymer hydrogelator, poly(3-sodium sulfo-p-phenylene-terephthalamide) polymer (NaPPDT), and water-soluble polymer with the polar group, poly(vinyl alcohol) (PVA) in various concentrations were examined. Molecular hydrogel composites formed from simple mixtures of NaPPDT aqueous solutions (0.1 wt.%~1.0 wt.%) and PVA aqueous solutions exhibited thixotropic behavior in the relatively low concentration region (0.1 wt.%~1.0 wt.%) and spinnable gel formation in the dense concentration region (4.0 wt.%~8.0 wt.%) with 1.0 wt.% NaPPDT aq., showing a characteristic concentration dependence of mechanical behavior. In contrast, each single-component aqueous solution showed no such gel formation in the concentration range in the present experiments. No gel formation behavior was also observed when mixed with common anionic polymers other than NaPPDT. This improvement in gel-forming ability due to mixing may be due to the increased density of the gel’s network structure composed of hydrogelator and PVA and rigidity owing to NaPPDT. | |||||||
| 言語 | en | |||||||
| bibliographic_information |
en : Gels 巻 9, 号 9, p. 679, 発行日 2023-08-23 |
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| 出版者 | ||||||||
| 出版者 | MDPI AG | |||||||
| 言語 | en | |||||||
| item_10001_source_id_9 | ||||||||
| 収録物識別子タイプ | EISSN | |||||||
| 収録物識別子 | 2310-2861 | |||||||
| item_10001_relation_14 | ||||||||
| 関連タイプ | isIdenticalTo | |||||||
| 識別子タイプ | DOI | |||||||
| 関連識別子 | https://doi.org/10.3390/gels9090679 | |||||||
| 権利 | ||||||||
| 権利情報 | © by the authors. | |||||||
| 言語 | en | |||||||
| 出版タイプ | ||||||||
| 出版タイプ | NA | |||||||
| 出版タイプResource | http://purl.org/coar/version/c_be7fb7dd8ff6fe43 | |||||||